Hydrogen bonding: HOC=O···H–N vs. HOC=O···H–C
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چکیده
منابع مشابه
Hydrogen bonding vs. halogen bonding: the solvent decides.
Control of intermolecular interactions is integral to harnessing self-assembly in nature. Here we demonstrate that control of the competition between hydrogen bonds and halogen bonds, the two most highly studied directional intermolecular interactions, can be exerted by choice of solvent (polarity) to direct the self-assembly of co-crystals. Competitive co-crystal formation has been investigate...
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hydrogen bonding is considered by many to be the ‘master key’ of molecular recognition — owing to its relatively predictable strength and directionality — and plays a major role in the assembly of diverse non-covalent assemblies1. Consequently, the study and exploitation of hydrogen bonds has been central to the development of modern supramolecular chemistry. In particular, numerous applied set...
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During the course of our systematic study of water molecule interactions, 1 we recently examined the potential energy surface for the neon atom-water molecule pair. 2 That examination produced an unanticipated feature, namely that a linear hydrogen bond forms, with the neon atom acting as a proton acceptor. By conventional standards,3 that hydrogen bond is weak (0.17 kcal/mole), and would there...
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ژورنال
عنوان ژورنال: Monatshefte für Chemie - Chemical Monthly
سال: 2014
ISSN: 0026-9247,1434-4475
DOI: 10.1007/s00706-014-1257-y